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Usually, you just create a user account, and that will also create the proper mail entries. SOme walkthroughs I've seen on the web use a mysql based user scheme for email, but I'm not a big fan, I like the flexibility that a real account has, like being able to ssh in to the box and check my mail using mutt.
Putting up a website means installing apache(or something else, but apache is the standard) and setting permissions. The apache portion of this page is pretty good [url=http://www.howtoforge.com/perfect-server-ubuntu-9.10-karmic-koala-ispconfig-2.